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It is useful to consider the step as the transition between two adjacent regions of a surface which are parallel to each other and thus identical in configuration — displaced from each other by an integral number of lattice planes.

Growing Crystals

Note here the distinct possibility of a step in a diffuse surface, even though the step height would be much smaller than the thickness of the diffuse surface. The surface advances normal to itself without the necessity of a stepwise growth mechanism. This means that in the presence of a sufficient thermodynamic driving force, every element of surface is capable of a continuous change contributing to the advancement of the interface. For a sharp or discontinuous surface, this continuous change may be more or less uniform over large areas each successive new layer.

For a more diffuse surface, a continuous growth mechanism may require change over several successive layers simultaneously. Non-uniform lateral growth is a geometrical motion of steps — as opposed to motion of the entire surface normal to itself. Alternatively, uniform normal growth is based on the time sequence of an element of surface. In this mode, there is no motion or change except when a step passes via a continual change.

The prediction of which mechanism will be operative under any set of given conditions is fundamental to the understanding of crystal growth.

crystal growth

Two criteria have been used to make this prediction:. Whether or not the surface is diffuse : a diffuse surface is one in which the change from one phase to another is continuous, occurring over several atomic planes. This is in contrast to a sharp surface for which the major change in property e. Whether or not the surface is singular : a singular surface is one in which the surface tension as a function of orientation has a pointed minimum.

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Growth of singular surfaces is known to requires steps, whereas it is generally held that non-singular surfaces can continuously advance normal to themselves. Consider next the necessary requirements for the appearance of lateral growth. It is evident that the lateral growth mechanism will be found when any area in the surface can reach a metastable equilibrium in the presence of a driving force. It will then tend to remain in such an equilibrium configuration until the passage of a step.

Afterward, the configuration will be identical except that each part of the step but will have advanced by the step height. If the surface cannot reach equilibrium in the presence of a driving force, then it will continue to advance without waiting for the lateral motion of steps. Thus, Cahn concluded that the distinguishing feature is the ability of the surface to reach an equilibrium state in the presence of the driving force.

He also concluded that for every surface or interface in a crystalline medium, there exists a critical driving force, which, if exceeded, will enable the surface or interface to advance normal to itself, and, if not exceeded, will require the lateral growth mechanism. Thus, for sufficiently large driving forces, the interface can move uniformly without the benefit of either a heterogeneous nucleation or screw dislocation mechanism.

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What constitutes a sufficiently large driving force depends upon the diffuseness of the interface, so that for extremely diffuse interfaces, this critical driving force will be so small that any measurable driving force will exceed it. Alternatively, for sharp interfaces, the critical driving force will be very large, and most growth will occur by the lateral step mechanism.

Note that in a typical solidification or crystallization process, the thermodynamic driving force is dictated by the degree of supercooling. Please see our Guide for Authors for information on article submission. If you require any further information or help, please visit our Support Center. This journal has partnered with Heliyon Physics, a dedicated section of Heliyon, an open access journal from Elsevier that publishes scientifically accurate and valuable research in physics. Heliyon Physics aims to make it easier for authors to share their research with a global audience quickly and easily, while benefitting from the subject-area expertise of specialized section editors, who ensure your work is considered fairly and reaches the right audience.

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Think data, software, materials and methods — what happens to these when your research project is finished? Search in:. Home Journals Journal of Crystal Growth. ISSN: Journal of Crystal Growth. Principal Editor: T. View Editorial Board.

Direction Controlled Growth of Organic Single Crystals by Novel Growth Methods

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The advent of semiconductor-based technology generated a demand for large, high-quality single crystals, not only of semiconductors but also of associated electronic materials. With increasing sophistication of semiconductor devices, an added degree of freedom in materials properties was obtained by varying the composition of major components of the semiconductor crystal over very short distances. Thin, multilayered single-crystal structures, and even structures that vary in composition both normal and lateral to the growth direction, are often required.

Bulk single crystals are usually grown from a liquid phase. The liquid may have approximately the same composition as the solid; it may be a solution consisting primarily of one component of the crystal; or it may be a solution whose solvent constitutes at most a minor fraction of the crystal's composition.

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  5. The most important bulk crystal growth technique is the crystal-pulling or Czochralski method, in which a rotating seed crystal is dipped into the melt Fig. Rotation reduces radial temperature gradients, and slow withdrawal of the rotating seed results in growth of a cylinder of single-crystal material. Crystal diameter and length depend upon the details of the temperature and pulling rate, and the dimensions of the melt container. Crystal quality depends very critically upon minimization of temperature gradients that enhance the formation of dislocations. Pulled silicon crystals 6 in. Ruby, sapphire, and group 13—15 compound semiconductor crystals are among the many crystals that are routinely grown by the Czochralski technique. The evolution of methods for the growth of very thin but very high-quality epitaxial layers has resulted largely from the need for such layers of semiconductors and magnetic garnets.

    The technique most closely related to the methods used for bulk crystal growth is liquid-phase epitaxy. For a typical binary semiconductor, growth is done onto a substrate single-crystal wafer from a solution rich in the component with the lowest partial pressure.

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    For a binary compound, the grown layers may differ only in impurity concentrations to modify their electrical characteristics. More often, multilayered structures with layers differing in major component composition but having the same crystal structure and lattice parameter are required.

    Growth by liquid-phase epitaxy is done in an apparatus in which the substrate wafer is sequentially brought into contact with solutions that are at the desired compositions and may be supersaturated or cooled to achieve growth. For crystalline solid solutions other than Al x Ga 1- x As, very precise control over solution compositions is required to achieve a lattice match. Typically, structures grown by liquid-phase epitaxy have four to six layers ranging widely in composition and having thickness from 10 -7 to 10 -6 m.

    The desirability of highly reproducible growth and even thinner epitaxial layers of 13—15 compounds on large wafer areas has led to the development of molecular-beam epitaxy and several forms of chemical-vapor deposition. Molecular-beam epitaxy is an ultrahigh-vacuum technique in which beams of atoms or molecules of the constituent elements of the crystal provided by heated effusion ovens, impinge upon a heated substrate crystal. It has been used for epitaxial layers as thin as 0.